To begin this first trick, turn your Rulers (Ctrl/Command+R) and Snap options on (Shift+Ctrl/Command+;).(Alternatively, via 'Window' menu option)
Open a new document ('Ctrl/Command+N') with a preference of your choice.
Here's mine below. As you can see the rulers visible.
Note the only thing in your 'Layer's Palette' is the default 'Background Layer'.
Now, from the 'Vertical (left) Ruler Bar' click and
SLOWLY drag a 'Guide' towards the center of this document. You should feel a slight
SNAP as you get close to the center.
Next, click on the 'Horizontal (top) Ruler Bar' and
SLOWLY drag a 'Guide' towards the center until, again, you feel a slight
Snap, then let go.
So now, any object on your canvas should
SNAP to the center of those converging guides.